A 3D porous cobalt-organic framework exhibiting spin-canted antiferromagnetism and field-induced spin-flop transition |
| |
Authors: | Huang You-Gui Yuan Da-Qiang Pan Long Jiang Fei-Long Wu Ming-Yan Zhang Xu-Dong Wei Wei Gao Qiang Lee Jeong Yong Li Jing Hong Mao-Chun |
| |
Affiliation: | State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Graduate School of the Chinese Academy of Sciences, Fujian, Fuzhou, 350002, China. |
| |
Abstract: | Two 3D cobalt-organic frameworks formulated as [Co3(2,4-pydc)2(micro3-OH)2]n.5nH2O (1) and [Co3(2,4-pydc)2(micro3-OH)2(H2O)]n.7nH2O (2) (2,4-pydc=pyridine-2,4-dicarboxylate) have been hydrothermally synthesized and characterized. Both compounds 1 and 2 exhibit the 3D porous frameworks with hydroxyl-bridged metal Delta-chains. However, in comparison with only two crystallographically independent CoII ions in a unit of 2, three crystallographically independent CoII ions are found in an asymmetric unit of 1, where their Delta-chains are constructed by two types of vertexes sharing quadrangles formed via edge-sharing triangles. Magnetic studies show that 1 exhibits spin-canted antiferomagnetism and a field-induced spin-flop transition while 2 behaves as a normal antiferromagnet. The magnetic properties are largely retained by the porous frameworks of dehydrated 1 and 2 compounds. Gas adsorption measurements indicate that both the dehydrated compounds absorb H2 into their pores. |
| |
Keywords: | |
本文献已被 PubMed 等数据库收录! |
|