Bimodal association of a bis-1,2,3-dithiazolyl radical |
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Authors: | Leitch Alicea A McKenzie Courtney E Oakley Richard T Reed Robert W Richardson John F Sawyer Lenora D |
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Affiliation: | Department of Chemistry, University of Waterloo, Waterloo, Ontario N2L 3G1, Canada. |
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Abstract: | The N-ethyl pyrazine-bridged bis-1,2,3-dithiazolyl radical (R(1) = Et) associates at room temperature as a C-C bonded sigma-dimer which, on heating, converts to a laterally S-S sigma-bonded structure. |
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