Synthesis, spectroscopic characterisation and X-ray structure of [trans-Co(en)2(NO2)2]2(Cr2O7) |
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| Authors: | Raj Pal Sharma Rajni Sharma Ritu Bala Juan M Salas and Miguel Quiros |
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| Institution: | (1) Department of Chemistry, Center of Advanced Studies, Panjab University, Chandigarh, 160014, India;(2) Departamento de Quimica Inorganica, Facultad de Ciencias, Universidad de Granada, 18071 Granada, Spain |
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| Abstract: | Dark red crystals of bistrans-dinitrobis(ethylenediamine)cobalt(III)] dichromate, trans-Co(en)2(NO2)2]2(Cr2O7) have been obtained by slowly allowing to mix the solutions of potassium dichromate and trans-dinitrobis(ethylenediamine)cobalt(III)
nitrate in 1:2 molar ratio in aqueous medium. Elemental analyses and spectroscopic techniques (IR, UV/visible, 1H and 13C NMR) were used for characterizing the complex salt. The complex salt crystallizes in the orthorhombic space group Fdd2 with
unit cell dimensions a = 24.778(2) ?, b = 30.457(2) ?, c = 6.5364(5) ?, Z = 8, V = 4932.8(7) ?3, R1 = 0.0617 and wR2 = 0.1518. X-ray structure determination revealed an ionic structure consisting of cationic cobaltammine trans-Co(en)2(NO2)2]NO3 and dichromate anion. It is the first crystal structure of this cation with a dianion. |
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| Keywords: | Ethylenediamine cobalt(III) coordination chemistry dichromate crystal structure |
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