Macromolecular metal complexes with transition-metal ions: Structure of a polymer and efficiency of complexation |
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Authors: | V D Pautov E V Anufrieva T D Anan’eva V B Lushchik T N Nekrasova R Yu Smyslov |
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Institution: | (1) Institute of Macromolecular Compounds, Russian Academy of Sciences, Bol’shoi pr. 31, St. Petersburg, 199004, Russia |
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Abstract: | A quantitative method of estimating the efficiency of formation of macromolecular metal complexes of carboxyl-containing (co)polymers with transition-metal ions in dilute solutions was developed. This method is based on the luminescence quenching of luminescently labeled macromolecules by transition-metal ions. With the use of this method, the effect of the chemical (including isomeric) structure of carboxyl-containing (co)polymers and external conditions on the stability of macromolecular metal complexes based on copper, nickel, and silver ions was assessed. With consideration for the data obtained, a targeted variation in the functional characteristics of macromolecular metal complexes may be accomplished. |
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