The outside knows the difference inside: trapping helium by immediate reduction of the orifice size of an open-cage fullerene and the effect of encapsulated helium and hydrogen upon the NMR of a proton directly attached to the outside |
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Authors: | Chuang Shih-Ching Murata Yasujiro Murata Michihisa Komatsu Koichi |
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Affiliation: | Institute for Chemical Research, Kyoto University, Uji, Kyoto, 611-0011, Japan. |
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Abstract: | A methodology to entrap He inside an open-cage fullerene by immediate reduction of the size of an orifice was developed, and the effects of encapsulated He and H(2) on the chemical shift of a proton directly attached to the outer fullerene sphere were revealed. |
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