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Synthesis and Structure of K_8[P_2W_18Mo_2Co_2O_68(H_2O)_2][MoO_6]·15H_2O
摘    要:Recently, Many tri-component heteropoly compounds have been synthesized, but tetra-component heteropoly compounds have not been reported. It is known that mixtures of Mo and Co oxides are a promoted hydrodesulphurization catalyst. The title compound is a polyoxophosphate containing Mo, Co and W, the divalent anion possesses two-fused Keggin structure, whereas MoO_6 has been confirmed to be an elementary structure unit of isopoly and heteropoly molybdates, but it, as an idependent anion, has not been reported either.

收稿时间:1993-10-04

Synthesis and Structure of K8[P2W18Mo2Co2O68(H2O)2][MoO6]·15H2O
ZHANG Heng-bin,YANG Guang-di,QI Xing-yi,LI Shu-jia,LI Zhong-hua. Synthesis and Structure of K8[P2W18Mo2Co2O68(H2O)2][MoO6]·15H2O[J]. Chemical Research in Chinese University, 1993, 9(4): 351-353
Authors:ZHANG Heng-bin  YANG Guang-di  QI Xing-yi  LI Shu-jia  LI Zhong-hua
Affiliation:1. Department of Chemistry, Jilin University, Changchun, 130023;
2. Department of Chemical Engineering, Harbin Shipbuilding Engineering Institute, Harbin, 150001
Abstract:
Keywords:Heteropolyacid  Synthesis  Structure  
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