aDepartment of Physics, 10-Vigyan Bhawan, University of Rajasthan, Jaipur 302004, India
bNuclear Science Centre, Aruna Asaf Ali Marg, New Delhi 110067, India
cUGC-DAE-CSR Kolkata Centre, LB/8 Bidhan Nagar, Kolkata 700098, India
Abstract:
Mn2+-doped CdS nanocrystals have been synthesized by adopting an aqueous solution precipitation method. These nanocrystals have been studied using X-ray diffraction (XRD), X-ray fluorescence (XRF), optical absorbance, photoluminescence (PL), DC electrical conductivity measurements and positron annihilation lifetime spectroscopy (PALS). The system has been found to be in the hexagonal phase. PL spectra have been studied on most prominent exciton peaks within the wavelength range (586–731 nm). The emission intensity is found to increase on increasing Mn2+ ion concentration (0–5%). Electrical conductivity lies within 0.819×10−6 to 1.69×10−6 Ω−1 m−1 and the system shows power law dependence for n=3–3.77. The Cd vacancies concentration has been found to decrease on increasing Mn%.