Spectrophotometric determination of nickel with cyclohexylidine-ammonium 2-aminocyclohexylidene-1-cyclohexene-1-dithiocarboxylate |
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Authors: | A. Safavi H. Parham |
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Affiliation: | Chemistry Department, College of Arts and Sciences, Shiraz University, Shiraz Iran |
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Abstract: | An (extraction)-spectrophotometric method is reported for the determination of nickel(II) with cyclohexylidineammonium 2-aminocyclohexylidene-l-cyclohexene-l-dithiocarboxylate. The violet 1:2 chelate is soluble in aqueous ethanolic or acetonic media at pH 6–9, or can be extracted into methyl isobutyl ketone. The molar absorptivity of the complex is about 2.5 × 104 l mol?1 cm?1 at 550 nm. |
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