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Separation and determination of inorganic anions by means of ion-pair chromatography
Authors:Alessandro Mangia  Maria Teresa Lugari
Institution:Istituto di Chimica Generale ed Inorganica, Universita'' di Parma, Via M. D''Azeglio 85, 43100 Parma Italy;Istituto di Chimica Farmaceutica e Tossicologica, Universita'' di Parma, Via M. D''Azeglio 85, 43100 Parma Italy
Abstract:Bromide, iodide, bromate, iodate, thiocyanate, nitrite and nitrate can be separated by means of ion-pair chromatography on a reversed-phase column (LiChrosorb RP2), using the tricaprylylmethylammonium ion (Aliquat-336) as counter ion in an acetonitrile-water mobile phase. The elution is monitored with an ultraviolet detector at 205 and 226 nm. The detection limits are in the low nanogram range.
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