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聚酰胺对水溶液中2,4-二硝基苯酚的吸附行为
引用本文:谢祖芳,夏金虹.聚酰胺对水溶液中2,4-二硝基苯酚的吸附行为[J].吉首大学学报(自然科学版),2002,23(1):69-73.
作者姓名:谢祖芳  夏金虹
作者单位:(1.玉林师范学院化学与生物系,广西 玉林 537000;2.桂林电子工业学院,广西 桂林 541004)
摘    要:研究了聚酰胺树脂吸附水溶液中2,4-二硝基苯酚的性能、条件及其影响因素.结果表明:聚酰胺树脂对2,4-二硝基苯酚具有较强的吸附能力,pH值是影响吸附的主要因素;吸附初段具有较快的动力学速度,中段速率与浓度符合二级反应动力学;吸附过程符合Flundlich 吸附等温式;用1% 氨水溶液可快速完全解吸;吸附过程属于一种基于氢键和范德华力的物理吸附范畴.

关 键 词:聚酰胺树脂  2  4-二硝基苯酚  吸附
文章编号:1007-2985(2002)01-0069-05
修稿时间:2001年9月4日

The Adsorption of 2, 4- binitro- phenol in Aqueous Solutions by Polyamide
XIE Zu fang ,XIA Jin hong.The Adsorption of 2, 4- binitro- phenol in Aqueous Solutions by Polyamide[J].Journal of Jishou University(Natural Science Edition),2002,23(1):69-73.
Authors:XIE Zu fang  XIA Jin hong
Institution:(1.Department of Chemistry and Biology,Yulin Teachers' College,Yulin 537000,Guangxi China;2.Guilin University of Electronic Technology,Guilin 541004,Guangxi China)
Abstract:The properties, optimal conditions and influencing factors for polyamide resin to adsorb 2,4-binitro-phenol from aqueous solutions have been investigated.The results show that polyamide has a better adsorption capability, and that the pH value is the main factor affecting adsorption; the initial rate of 2,4-binitro-phenol adsorption on polyamide is faster, and the middle rate is second-order with respect to its concentration.The adsorption process in solution exhibits Freundlich behavior and is mainly physical adsorption.The 2,4-binitro-phenol adsorbed on the resin can be eluted by 1% ammoniac solution quickly.
Keywords:polyamide  2  4-binitro-phenol  adsorption
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