Direct coupling of benzene with olefin catalyzed by Pd(OAc)(2) combined with heteropolyoxometalate under dioxygen |
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| Authors: | Yokota Takahiro Tani Masayuki Sakaguchi Satoshi Ishii Yasutaka |
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| Institution: | Department of Applied Chemistry, Faculty of Engineering, Kansai University, Suita, Osaka 564-8680, Japan. |
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| Abstract: | The oxidative coupling reaction of benzenes with alkenes was successfully achieved by the Pd(OAc)(2)/molybdovanadophosphoric acid (HPMoV)/O(2) system. For example, the reaction of benzene with ethyl acrylate by the above catalytic system in acetic acid afforded ethyl cinnamate as a major product in satisfactory yield. |
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