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Vibrational spectra and structure of N-tozyl(4-dimethylamino)-pyridinium salts
Affiliation:1. Innovation Center of Pesticide Research, Department of Applied Chemistry, College of Science, China Agricultural University, Beijing 100193, People''s Republic of China;2. Key Laboratory of National Forestry and Grassland Administration on Pest Chemical Control, Beijing 100193, People''s Republic of China;3. Jilin Provincial Key Laboratory of Animal Resource Conservation and Utilization, Northeast Normal University, Changchun, Jilin 116000, People''s Republic of China;4. Key Laboratory of Vegetation Ecology, MOE, Northeast Normal University, Changchun, Jilin 116000, People''s Republic of China
Abstract:Normal vibrations and absorption band forms for N-tozyl(4-dimethylamino)pyridinium cation have been calculated in the harmonic approximation. On the basis of this calculation complete interpretation for N-tozyl(4-dimethylamino)pyridinium salts with Cl, Br, ClO4 and BPh4 anions has been carried out; several conclusions are made concerning the structure of the compounds under investigations.
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