Zn(II) and Co(II) 3D Coordination Polymers Based on 2-Iodoterephtalic Acid and 1,2-bis(4-pyridyl)ethane: Structures and Sorption Properties |
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| Authors: | Alexander S. Zaguzin Taisiya S. Sukhikh Ilyas F. Sakhapov Vladimir P. Fedin Maxim N. Sokolov Sergey A. Adonin |
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| Affiliation: | 1.South Ural State University, Lenina St. 76, 454080 Chelyabinsk, Russia; (A.S.Z.); (I.F.S.);2.Nikolaev Institute of Inorganic Chemistry, SB RAS, Lavrentieva St. 3, 630090 Novosibirsk, Russia; (T.S.S.); (V.P.F.); (M.N.S.);3.Arbuzov Institute of Organic and Physical Chemistry, RAS, Arbuzov St. 8, 420088 Kazan, Russia |
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| Abstract: | Metal-organic frameworks [M2(2-I-bdc)2bpe] (M = Zn(II) (1), Co(II) (2), 2-I-bdc = 2-iodoterephtalic acid, and bpe = 1,2-bis(4-pyridyl)ethane) were prepared and characterized by X-ray diffractometry. Both compounds retain their 3D structure after the removal of guest DMF molecules. Selectivity of sorption of different organic substrates from the gas phase was investigated for both complexes. |
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| Keywords: | zinc metal-organic frameworks coordination polymers carboxylates sorption |
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