Electric-field-induced two-photon processes |
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Institution: | 1. Department of Psychiatry, University of Kinshasa, Lemba, Kinshasa, Democratic Republic of Congo;2. Department of Psychiatry and Mental Health, Kampala International University Western Campus, Ishaka-Bushenyi, Uganda |
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Abstract: | In this paper we outline the novel features associated with two-photon processes in the presence of intense static electric fields. Both electrical polarisation effects and non-linear electro-optical effects are discussed, and their likely orders of magnitude estimated. It is illustrated how the interaction of the electric field with a molecular centre can lead to a relaxation of conventional two-photon selection rules, allowing spectroscopic access to otherwise forbidden excited states. Selection rules for the electro-optical channel are tabulated for some of the more common point groups. |
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