Effect of the dispersity of substances on the macrokinetics of thermal analysis under non-isothermal conditions |
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Authors: | V A Logvinenko L I Myachina |
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Institution: | (1) Institute of Inorganic Chemistry, Sibirian Department of the Academy of Sciences of the USSR, Novosibirsk, USSR |
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Abstract: | The effect of the dispersity of the sample on the topochemical mechanism and on the kinetic parameters of thermolysis (A
s Bs + Cg) under non-isothermal conditions is discussed. For correctness of the experiment, a ratio of maximum and minimum particle diameters 6 is a necessary condition. The topochemical mechanism of the process should be determined separately for the initial and final stages.
Zusammenfassung Die Wirkung der Dispersion der Probe auf den topochemischen Mechanismus und die kinetischen Parameter der Thermolyse (As Bs + Cg) unter nichtisothermen Bedingungen wird diskutiert. Die Genauigkeit des Experiments setzt ein Verhältnis der maximalen und minimalen Teilchendurchmesser von 6 voraus. Der topochemische Mechanismus sollte für die Anfangs- und Endphase des Vorganges einzeln bestimmt werden.
Résumé L'effet de la dispersion de l'échantillon sur le mécanisme topochimique et sur les paramètres cinétiques de la thermolyse (As Bs + Cg) en conditions non-isothermes est discuté. La conditions nécessaire pour qu'une expérience soit correcte est que le rapport entre les valeurs maximale et minimale des diamètres des particules soit 6. Le mécanisme topochimique du processus devrait être déterminé séparément pour les étapes initiale et finale.
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