Influence of Preparation Conditions on Structural Stability of Ordered Mesoporous Carbons Synthesized by Evaporation-induced Triconstituent Co-assembly Method

Various ordered mesoporous carbons (OMCs) have been prepared by evaporation-induced triconstituent co-assembly method. Their mesostructural stability under different carbon content, aging time and acidity were conveniently monitored by X-ray diffraction, transmis-sion electron microscopy, and N₂ sorption isotherms techniques. The results show mesostruc-tural stability of OMCs is enhanced as the carbon content increases from 36% to 46%, further increasing carbon content deteriorates the mesostructural stability. Increasing aging time from 0.5 h to 5.0 h make the mesostructural stability go through an optimum (2.0 h) and gradually reduce framework shrinkage of the OMCs. Highly OMCs can only be obtained in the acidity range of 0.2～1.2 mol/L HCl, when the acidity is near the isoelectric point of silica, the resulting OMCs have the best mesostructure stability. Under the optimum condi-tion, the carbon content of 46%, aging time of 2.0 h, and 0.2 mol/L HCl, the resulting OMCs have the best mesostructure stability and the highest BET surface areas of 2281 m²/g.