Hydroxylamine Reactions with Peroxide Products of Alkenes Ozonolysis |
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Authors: | Yu. V. Legostaeva L. R. Garifullina I. S. Nazarov N. M. Ishmuratova G. Yu. Ishmuratov |
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Affiliation: | 1.Ufa Institute of Chemistry,Russian Academy of Sciences,Ufa, Bashkortostan,Russia |
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Abstract: | Reactions were studied of peroxide ozonolysis products obtained from linear and cyclic alkenes with hydroxylamine prepared in situ from NH2OH·HCl by hydrogen chloride neutralization with sodium acetate. A one-pot reactions sequence was performed: alkene oxidation with ozone → reduction to a carbonyl compound with hydroxylamine → condensation of the carbonyl compound with hydroxylamine providing a possibility of direct transformation of alkenes in keto- and aldoximes excluding the stage of preparation and isolation of the carbonyl compound. |
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