首页 | 本学科首页   官方微博 | 高级检索  
     检索      


Geminal Dicationic Ionothermal Synthesis of One Three-Dimensional Luminescent Strontium(II) Coordination Polymer Based on 1,4-Naphthalenedicarboxylate Acid
Authors:W J Zhu  Z J Qin  Y Bai  D B Dang
Institution:1.Henan Key Laboratory of Polyoxometalate Chemistry, Institute of Molecular and Crystal Engineering, College of Chemistry and Chemical Engineering,Henan University,Kaifeng,P.R. China
Abstract:One three-dimensional Sr(II) coordination polymer C6(MIm)2]Sr3(1,4-NDC)4] (I) (C6(MIm)2 = 1,3-bis(3-methylimidazolium-1-yl)hexyl, 1,4-H2NDC = 1,4-naphthalenedicarboxylate acid) has been synthesized using an ionothermal method and structurally characterized by IR spectroscopy, UV-Vis spectroscopy, XRPD, and X-ray single-crystal structure analysis (СIF file CCDC 1033958). Two types of strontium centers are bridged by two coordination modes of 1,4-H2NDC ligands to form a Sr(II) chain. Each Sr(II) chain is crossconnected to four other chains to generate a 3D coordination polymer, in which C6(MIm) 2 2+ cations as charge balancing species are filled in the channels of the anionic framework. The polymeric solid of I exhibits strong luminescent emission at room temperature.
Keywords:
本文献已被 SpringerLink 等数据库收录!
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号