Modification of Phosphoryl Substituents of Phthalocyanines As a Route to Targeted Tuning of Lipophilic-Hydrophilic Properties |
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| Authors: | I P Kalashnikova D V Baulin V E Baulin A Yu Tsivadze |
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| Institution: | 1.Institute of Physiologically Active Compounds,Russian Academy of Sciences,Chernogolovka,Russia;2.Frumkin Institute of Physical Chemistry and Electrochemistry,Russian Academy of Sciences,Moscow,Russia |
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| Abstract: | О′,О′-Diethyl-2-(3,4-dicyanophenoxy)phenyl]phosphonate has been synthesized for the first time and introduced in template condensation on lithium and zinc cations to prepare a series of new neutral and acidic phthalocyanines containing four fragments of 2-oxyphenylphosphonic acid. A scheme of modification of the peripheral substituents at the phosphoryl group was developed allowing a targeted synthesis of phthalocyanine ligands and complexes soluble in organic solvents or aqueous media. |
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