Anomalous optical response with variation in band filling in linear chain conductors

We report the polarized infrared reflectance of ($\text{N}$-methylphenazinium)_x (phenazine)_1-x(tetracyanoquinodimethanide), (NMP)_x(Phen)_1-x(TCNQ) for 0.5≤x≤1.0. We demonstrate that the “Drude edge” in TCNQ salts is related to the conduction electron charge density. An anomalous rapid red shift of the plasma frequency, observed for $\text{x ～}\text{2}\text{3}$, may signal the emptying of the conduction electrons from half of the chains and/or a crossover from small U/W (coulomb repulsion/bandwidth) to large U/W behavior.