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Thermodynamics of the extraction of europium(III) radiotracer by benzyl-phosphonic acid monoester
Authors:E A Saad  A M El-Atrash
Institution:(1) Chemistry Department, Faculty of Science, Ain Shams University, Abbassia, Cairo, (Egypt)
Abstract:The extraction of Eu3+ from perchloric acid by ethyl hydrogen benzyl phosphonate (HEBP) dissolved in a series of organic diluents, has been studied at different temperatures. From the variation of the distribution ratio with temperature, the thermodynamic functions DeltaH, DeltaS and DeltaG have been determined. The meaning of the experimentally obtained thermodynamic quantities is discussed.
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