Electronic structures and electron detachment energies of halogen substituted acetate anions, XCH2COO- (X=F,Cl,Br) |
| |
Authors: | Yu Wenbo Lin Zijing Ding Chuanfan |
| |
Institution: | Hefei National Laboratory for Physical Sciences at the Microscale, University of Science and Technology of China, Hefei 230026, China. |
| |
Abstract: | The electronic structures and the halogen inductive effects on the acetate anion were investigated in XCH2COO- (X=F,Cl,Br) by photoelectron spectroscopy (PES) and ab initio calculations. The PES spectra indicated that the electron binding energies increased in the order of FCl>Br. These systematic changes of detachment energy and IPs were explained by examining the charge redistributions upon detaching electrons. |
| |
Keywords: | |
本文献已被 PubMed 等数据库收录! |
|