Synthetic approach to grayanotoxins: a new method for the construction of the a-homograyanotoxane ring system |
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Authors: | Tetsuji Kametani Hiroo Matsumoto Toshio Honda Keiichiro Fukumoto |
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Affiliation: | Pharmaceutical Institute, Tohoku University, Aobayama, Sendai 980, Japan |
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Abstract: | The A-homograyanotoxane ring system was constructed by a thermolysis of benzocyclobutene, followed by a Wagner-Meerwein rearrangement of the resulting kaurane type of compound. |
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