Contiguous concerted participation in the rearrangement of <span class="math"><math><mtext>anti</mtext></math></span>-tricyclo[4.2.1.1.<sup>2,5</sup>]deca-3,7,-diene-9,10-diol,a highly hindered system.期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

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Contiguous concerted participation in the rearrangement of $anti$ -tricyclo[4.2.1.1.^2,5]deca-3,7,-diene-9,10-diol,a highly hindered system.

Authors:	Christopher W Doecke Peter J Garratt

Institution:	Department of Chemistry, University College London, London, WC1H OAJ UK

Abstract:	The acid catalysed peclppangement of anti-tricyclo4.1.1.^2,5]deca-3,7-diene-9, 10-diol ( $1a$ ) to $2a$ is shown to proceed through concommitant electrophilic and nucleophilic attack on an alkene by an incipient carbonium ion and the rernaining alcohol function.

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