The effect of pressure on the oxidation of benzhydrol by alkaline permanganate |
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| Authors: | Neil S Isaacs Karel AH Heremans |
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| Institution: | Department of Chemistry, University of Reading, Reading, RG6 2AD Belgium;Department of Physical Chemistry, Catholic University of Leuven, 200D Leuven B3030, Belgium |
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| Abstract: | The rate of oxidation of benzhydrol and benzhydrol-d to benzophenone by alkaline permanganate has been measured over a pH range 10 to 12.5 and pressures from 1 to 1000 bar. The pressure effect on the rate is small, Δ≠ = ?6 to ?8 cm3mol?1. This is held to support a hydrogen atom transfer in the rate-determining step. |
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