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Catalyzed insertion reactions of substituted α-diazoesters. A new synthesis of cis-enoates |
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| Authors: | Nobuo Ikota Norio Takamura Stanley D Young Bruce Ganem |
| Institution: | Department of Chemistry Baker Laboratories Cornell University Ithaca, New York 14853 USA |
| Abstract: | The decomposition of α-diazoesters is notably catalyst-dependent; with rhodium (II) carboxylates a stereoselective insertion reaction leads to the title structures in high yield. |
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