Reaction of lithium dimethylcuprate with conformationally biased β-acyloxy enol esters - regio and stereocontrolled access to functionalized six-carbon chiral synthons |
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| Authors: | Stephen Hanessian Peter C Tyler Yves Chapleur |
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| Institution: | Department of Chemistry, University of Montreal Montreal, Quebec, Canada, H3C 3VI |
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| Abstract: | Alkyl 2-acyloxy α-D-erythro-hex-2-enopyranoside diesters, readily available from D-hexoses, are versatile intermediates fro the expeditious preparation of six-carbon chiral synthons containing alternating and/or consecutive C-methyl and hydroxyl groups. |
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