Starke verdrillungen trotz schwacher sterischer hinderung |
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Authors: | Armin Berndt Rainer Schnaut Wilhelm Ahrens |
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Institution: | Fachbereich Chemie der Universität Marburg, Hans-Meerwein-Strasse, D-3550 Marburg Germany |
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Abstract: | Considerable twisting of weakly hindered hydrazonyl radicals is explained on the basis of a low barrier to rotation due to compensation of the loss of π-π-delocalization on twisting by gain of π-σ-delocalization. |
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