Oxidation of amines and sulfides by 3-bromo-4,5-dihydro-5-hydroperoxy-4,4-dimethyl-3,5-diphenyl-3h-pyrazole |
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| Authors: | Alfons L Baumstark Douglas R Chrisope |
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| Institution: | Department of Chemistry, Laboratory for MBS, Georgia State University, Atlanta, Georgia 30303 USA |
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| Abstract: | The reaction of 3-bromo-4,5-dihydro-5-hydroperoxy-4,4-dimethyl-3,5-diphenyl-3H-pyrazole with tertiary amines and sulfides produced amine oxides and sulfoxides in high yield with k2's for amines similar to those reported for reaction of amines with a 4a-hydroperoxyflavin. |
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