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A new optical resolution method of tertiary acetylenic alcohol utilizing complexation with brucine
Authors:Fumio Toda  Koichi Tanaka  Hideo Ueda
Institution:Department of Chemistry, Faculty of Engineering, Ehime University, Matsuyama 790, Japan;Central Research Laboratory, Ube Industries, Ltd., Ube 755, Japan
Abstract:Some tertiary acetylenic alcohols were resolved efficiently utilizing complexation with brucine. The crystal structure of 1:1 brucine complex of 1-(o-bromophenyl)-1-phenyl-2-propynol (1d) was reported.
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