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Photochemical generation of tetramethyldisilene and photoinduced 1,2-silyl-migration |
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| Authors: | Yasuhiro Nakadaira Tatsuo Otsuka Hideki Sakurai |
| Affiliation: | Department of Chemistry, Faculty of Science, Tohoku University, Sendai 980 Japan |
| Abstract: | Described herein is the first clear evidence of the photochemical generation of tetramethyldisilene which can be efficiently trapped by dienes. An intriguing 1,2-photo-induced silyl migration is also reported. |
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