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[2+2]-Cycloadditionen von vinylkationen
Authors:Michael Hanack  Ingo Harder  Klaus-Rainer Bofinger
Affiliation:Institut für Organische Chemie der Universität Tübingen Lehrstuhl für Organische Chemie II, 7400 Tübingen, Germany
Abstract:The vinylbromides 1a and 1b are allowed to react ith AgBF4 and AgPF6 in the presence of various olefins in CH2Cl2 as the solvent. Except for the reaction of cyclopentene with 1a all other olefins used, react with vinyl cation 2 to form the cycloaddition products 7, 8a and 8b in high yields.
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