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Ultrasound effect on the aromatic nucleophilic substitution reactions on some haloarenes
Authors:Meciarová Mária  Toma Stefan  Magdolen Peter
Affiliation:Department of Organic Chemistry, Faculty of Natural Sciences, Comenius University, Mlynská dolina CH-2, SK-842 15 Bratislava, Slovak Republic. mmeciarova@fns.uniba.sk
Abstract:The sonochemical nucleophilic aromatic substitutions on haloarenes with different amines have been studied. A beneficial ultrasound effect was observed and high yields of the products were obtained after 15-30 min sonication. The reaction course of the nucleophilic aromatic substitution was found to be strongly dependent on nucleophilicity, bulkiness, and boiling point of amines as well as on the electron-withdrawing property of the substituents on the haloarenes.
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