| New Supramolecular Complex Assembled through Hydrogen Bonds. Crystal Structure of Co(PMBP-tsc)_2 ·2DMF·2H_2O |
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| 引用本文： | 刘浪
,贾殿赠
,乔永民
,郁开北.New Supramolecular Complex Assembled through Hydrogen Bonds. Crystal Structure of Co(PMBP-tsc)_2 ·2DMF·2H_2O[J].中国化学,2002,20(3):286-291. |
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| 作者姓名： | 刘浪 贾殿赠 乔永民 郁开北 |
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| 作者单位： | LIU，Lang JIA，Dian-Zeng QIAO，Yong-Min YU，Kai-Bei aInstitute of Applied Chemistry，Xinjiang University，Urumqi，Xinjiang 830046，China bChengdu Institute of Organic Chemistry，Chinese Academy of Sciences，Chengdu，Sichuan 610012，China |
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| 基金项目： | ProjectsupportedbytheNationalNaturalScienceFoundationofChina (No.2 986 10 0 2 ) |
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| 摘 要： | ＩｎｔｒｏｄｕｃｔｉｏｎＭｏｌｅｃｕｌａｒｐｏｌｙｍｅｒｓｗｉｔｈｏｎｅｄｉｍｅｎｓｉｏｎａｌｏｒｍｕｌｔｉ ｄｉｍｅｎｓｉｏｎａｌｓｔｒｕｃｔｕｒｅａｓｓｅｍｂｌｅｄｔｈｒｏｕｇｈｈｙｄｒｏｇｅｎｂｏｎｄｓｉｓａｎｉｍｐｏｒｔａｎｔｒｅｓｅａｒｃｈｃｏｎｔｅｎｔｉｎｔｈｅｓｕｐｒａ ｍｏｌｅｃｕｌａｒｃｈｅｍｉｓｔｒｙａｎｄｃｒｙｓｔａｌｅｎｇｉｎｅｅｒｉｎｇ .1,2 Ｗｉｔｈｔｈｅｄｅｖｅｌｏｐ ｍｅｎｔｏｆｎｅｗｔｙｐｅｆｕｎｃｔｉｏｎａｌｍａｔｅｒｉａｌｓｓｕｃｈａｓｍｏｌｅｃｕｌａｒｍａｇｎ…
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New Supramolecular Complex Assembled through Hydrogen Bonds. Crystal Structure of Co (PMBP‐tsc)2 · 2DMF · 2H2O |
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| LIU,Lang JIA,Dian-Zeng QIAO,Yong-Min YU,Kai-Bei aInstitute of Applied Chemistry,Xinjiang University,Urumqi,Xinjiang ,China bChengdu Institute of Organic Chemistry,Chinese Academy of Sciences,Chengdu,Sichuan ,China.New Supramolecular Complex Assembled through Hydrogen Bonds. Crystal Structure of Co (PMBP‐tsc)2 · 2DMF · 2H2O[J].Chinese Journal of Chemistry,2002,20(3):286-291. |
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| Authors: | LIU Lang JIA Dian-Zeng QIAO Yong-Min YU Kai-Bei aInstitute of Applied Chemistry Xinjiang University Urumqi Xinjiang China bChengdu Institute of Organic Chemistry Chinese Academy of Sciences Chengdu Sichuan China |
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| Institution: | LIU,Lang JIA,Dian-Zeng QIAO,Yong-Min YU,Kai-Bei aInstitute of Applied Chemistry,Xinjiang University,Urumqi,Xinjiang 830046,China bChengdu Institute of Organic Chemistry,Chinese Academy of Sciences,Chengdu,Sichuan 610012,China |
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| Abstract: | The structure of the complex Co (PMBP‐tsc)2 · 2DMF · 2H2O] (PMBP‐tsc = l‐phenyl‐3‐methyl‐4‐benzoylpyrazol‐5‐one‐thio‐semicarbazone) has been determined by X‐ray crystallography. It crystallizes in the orthorhombic system, space group Pna21, with lattice parameters a = 2.1170 (3) nm, b = 1.2780 (10) nm, c = 1.8956 (2) nm, V = 4.5258 (9) nm3 and Z = 4. The structure shows that Co2+ in the complex is hexa‐coordinated with a distorted octahedral coordination sphere. The water molecules bridge the adjacent stacks through hydrogen bonds and lead to supramolecular formation with three‐dimensional network structure. |
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| Keywords: | cobalt(II) compound crystal structure supra~mole~cule hydrogen bonds |
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