Asymmetric Catalytic Preparation of Polysubstituted Cyclopropanol and Cyclopropylamine Derivatives |
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| Authors: | Marwan Simaan Prof Dr Ilan Marek |
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| Institution: | The Mallat Family Laboratory of Organic Chemistry, Schulich Faculty of Chemistry, Technion-Israel Institute of Technology, Haifa, Israel |
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| Abstract: | The catalytic asymmetric carbometalation of cyclopropenes followed by either an electrophilic oxidation or amination reaction provides a unique approach to the formation of diastereomerically pure and enantiomerically enriched cyclopropanol and cyclopropylamine derivatives, respectively. |
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| Keywords: | amination carbometalation cyclopropanols cyclopropylamines oxidation |
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