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Spectroscopic Evidence for Ligand Substitution Reactions at the Solid–Liquid Interface of a Sub‐micrometer Gold(I) Carbene Complex |
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| Authors: | Daniel Langford Dr. Mirjana Đurović Dr. Marcin Oszajca Dr. Joanna Kuncewicz Prof. Dr. Rudi van Eldik |
| Affiliation: | 1. Faculty of Chemistry, Jagiellonian University, Krakow, Poland;2. Department of Chemistry, University of Konstanz, Konstanz, Germany;3. Department of Chemistry and Pharmacy, University of Erlangen-Nuremberg, Erlangen, Germany |
| Abstract: | Colloidal coordination compounds in the sub‐micrometer range were synthesized from a chloro gold(I) carbene complex via the anti‐solvent procedure and stabilized by a surfactant shell of Tween 20. This compound was successfully applied as model system to monitor heterogeneous multiphase ligand substitution reactions at the solid–liquid interface. |
| Keywords: | colloids gold halide ligands heterogeneous reactions multiphase systems |