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Removal of tetramethyl ammonium hydroxide from synthetic liquid wastes of electronic industry through micellar enhanced ultrafiltration
Authors:Francesco Tortora  Valentina Innocenzi  Ida De Michelis  Francesco Vegliò  Giuseppe Mazziotti di Celso
Institution:1. Dipartimento di Ingegneria Industriale e dell’Informazione e di Economia, Università dell’Aquila, L’Aquila, Italy;2. Faculty of Bioscience, University of Teramo, Teramo, Italy
Abstract:In this paper, the separation of tetramethyl ammonium hydroxide (TMAH) from synthetic liquid wastes of electronic industry is carried out by using a micellar enhanced ultrafiltration (MEUF) process. This treatment represents the first step of an integrated process, aimed at the recovery of TMAH and surfactant and water reuse. The laboratory tests are carried out with an ultrafiltration module using initial solutions having a concentration of pollutant equal to 2?g/L and by adding sodium dodecyl sulfate as a surfactant, at a concentration in the range 4–10?mM/L, that is, under and above its critical micellar concentration (CMC). The experiments have been carried out at a fixed temperature of 25°C. The obtained results showed that very good percentage removals of TMAH are achieved (99%), especially when the surfactant was above the CMC.
Keywords:Electronic industry  MEUF  sodium dodecyl sulfate  tetramethyl ammonium hydroxide  ultrafiltration  water reuse
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