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A Metal–Organic Framework with Exceptional Activity for C−H Bond Amination |
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| Authors: | Dr Le Wang Douglas W Agnew Xiao Yu Prof Dr Joshua S Figueroa Prof Dr Seth M Cohen |
| Institution: | 1. Department of Chemistry and Biochemistry, University of California, San Diego, La Jolla, CA, USA;2. Department of Nanoengineering, University of California, San Diego, La Jolla, CA, USA |
| Abstract: | The development of catalysts capable of fast, robust C?H bond amination under mild conditions is an unrealized goal despite substantial progress in the field of C?H activation in recent years. A Mn‐based metal–organic framework (CPF‐5) is described that promotes the direct amination of C?H bonds with exceptional activity. CPF‐5 is capable of functionalizing C?H bonds in an intermolecular fashion with unrivaled catalytic stability producing >105 turnovers. |
| Keywords: | amination heterogeneous catalysis manganese metal– organic frameworks nitrenes |