Coordination-insertion copolymerization of allyl monomers with ethylene |
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| Authors: | Ito Shingo Kanazawa Masafumi Munakata Kagehiro Kuroda Jun-ichi Okumura Yoshikuni Nozaki Kyoko |
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| Institution: | Department of Chemistry and Biotechnology, Graduate School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan. |
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| Abstract: | Coordination-insertion copolymerization of allyl monomers with ethylene was developed by using a palladium/phosphine-sulfonate catalyst. A variety of allyl monomers, including allyl acetate, allyl alcohol, protected allylamines, and allyl halides, were copolymerized with ethylene to form highly linear copolymers that possess in-chain -CH(2)CH(CH(2)FG)- units. |
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