Rhodium(III)-catalyzed arylation of Boc-imines via C-H bond functionalization |
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| Authors: | Tsai Andy S Tauchert Michael E Bergman Robert G Ellman Jonathan A |
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| Affiliation: | Department of Chemistry, Yale University, New Haven, Connecticut 06520, United States. |
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| Abstract: | The first rhodium-catalyzed arylation of imines proceeding via C-H bond functionalization is reported. Use of a non-coordinating halide abstractor is important to obtain reactivity. Aryl-branched N-Boc-amines are formed, and a wide range of functionality is compatible with the reaction. |
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