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碲化镉量子点/聚吡咯纳米复合物的发光性质研究
引用本文:叶孙洁,陆云. 碲化镉量子点/聚吡咯纳米复合物的发光性质研究[J]. 光散射学报, 2011, 23(4): 352-356
作者姓名:叶孙洁  陆云
作者单位:南京大学化学化工学院高分子科学与工程系,配位化学国家重点实验室,南京210093
基金项目:国家自然科学基金(20974043)
摘    要:通过原位种子聚合构筑了碲化镉量子点(CdTe QDs)/聚吡咯(PPy)纳米复合物。利用透射电镜、红外光谱及荧光发射光谱对其形貌、结构、光致发光性质进行了测试分析。研究结果表明, 复合物中CdTe量子点结晶良好。复合物中两组分间能级耦合相互作用使量子点表面陷阱态钝化, 从而导致对应CdTe量子点带间跃迁的410 nm发光峰的出现, 显示了复合物作为光电器件材料的潜在应用价值。

关 键 词:碲化镉量子点  聚吡咯  纳米复合物  发光性质
收稿时间:2011-06-30

Luminescent property of CdTe/PPy Nanocomposites
YE Sun-jie , LU Yun. Luminescent property of CdTe/PPy Nanocomposites[J]. Chinese Journal of Light Scattering, 2011, 23(4): 352-356
Authors:YE Sun-jie    LU Yun
Affiliation:(Department of Polymer Science and Engineering,State Key Laboratory of Coordination Chemistry,School of Chemistry and Chemical Engineering,Nanjing University,Nanjing 210093,China)
Abstract:CdTe/PPy nanocomposites are fabricated by in situ seed polymerization.The morphology,structure,emission properties are characterized by using TEM,FT-IR and fluorescent spectroscopy.The results suggest that the CdTe quantum dots crystallize well in the CdTe/PPy nanocomposties.The peak at 410nm in emission spectrum of CdTe/PPy nanocomposite is considered as the result arose from the interaction between CdTe quantum dot and PPy,which indicates the potential application of the nanocomposites as optoelectronic and photovoltaic devices.
Keywords:CdTe quantum dots  PPy  nanocomposite  luminescent property
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