Structure of the complex of hexanuclear manganese pivalate with isonicotinamide |
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| Authors: | E. Yu. Fursova V. I. Ovcharenko A. S. Bogomyakov G. V. Romanenko |
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| Affiliation: | 11024. International Tomography Center, Siberian Division, Russian Academy of Sciences, Novosibirsk, Russia
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| Abstract: | The structure of the [Mn6(O)2(Piv)10L2]∞ compound, where Piv is the pivalate anion and L is isonicotinamide, is investigated. Its solid phase is found to be formed by polymeric layers within which hexanuclear fragments {Mn6(O)2(Piv)10} are bound by bidentate bridging L. The molecules of the solvent (Me2CO or EtOAc) in which the synthesis was performed are incorporated into the inter-layer space of the crystal. |
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