Reductive elimination of C6F5-C6F5 in the reaction of bis(pentafluorophenyl)palladium(II) complexes with protic acids |
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| Authors: | Koizumi Take-aki Yamazaki Atsuko Yamamoto Takakazu |
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| Affiliation: | Chemical Resources Laboratory, Tokyo Institute of Technology, 4259 Nagatsuta, Yokohama 226-8503, Japan. |
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| Abstract: | Reductive elimination of C6F5-C6F5 from cis-[Pd(C6F5)2L] (L = cod, bpy, and dppb) was promoted by Br?nsted acids. HNO3 is a convenient acid for the formation of C6F5-C6F5 from [Pd(C6F5)2(cod)]. The products are controlled by the auxiliary ligand. |
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