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Excitation of inner-shell states of CO2, COS,CS2, N2O and C2H2 by low energy electron impact
Institution:1. Institut für Ionenphysik und Angewandte Physik and Center for Molecular Biosciences Innsbruck (CMBI), Leopold Franzens Universität Innsbruck, Technikerstrasse 25, 6020 Innsbruck, Austria;2. Université de Lyon, Université Claude Bernard Lyon 1, CNRS/IN2P3, UMR5822, Institut de Physique Nucléaire de Lyon, 43 Bd du 11 novembre 1918, 69622 Villeurbanne, France;3. Medicinal and Process Chemistry Division, CSIR-Central Drug Research Institute, Lucknow 226 031, India;4. Analytical Chemistry and Mass Spectrometry Division, CSIR-Indian Institute of Chemical Technology, Hyderabad 500 007, India;1. Indian Centre For Space Physics, 43 Chalantika, Garia Station Road, Kolkata 700084, India;2. S.N. Bose National Center for Basic Sciences, JD-Block, Salt Lake, Kolkata 700098, India
Abstract:The design of an electron impact spectrometer for use in the study of inner-shell electric-dipole-forbidden transitions is described. The use of the spectrometer to investigate spin-forbidden transitions to inner-shell excited states of CO2, COS, CS2, N2O and C2H2 is reported. For all these molecules, excitation of inner-shell triplet states has been observed.
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