X-ray photoelectron spectroscopy of merocyanine dyes: III. Structure of the O1s line in the merocyanine 540 dye |
| |
| Affiliation: | 1. Materials Measurement Lab, National Institute of Standards Technology, Gaithersburg, MD 20899, USA;2. Center for Nanoscale Science and Technology, National Institute of Standards Technology, Gaithersburg, MD 20899, USA;3. Department of Chemistry and Center for Nanostructured Electronic Materials, University of Florida, Gainesville, FL 32611, USA;4. Center for Functional Nanomaterials, Brookhaven National Laboratory, Upton, NY 11793, USA;1. Department of Mechanical Engineering, Yonsei University, Yonsei-ro 50, Seodaemun-gu, Seoul 03722, Republic of Korea;2. Department of Chemical and Biomolecular Engineering, Yonsei University, Yonsei-ro 50, Seodaemun-gu, Seoul 03722, Republic of Korea;3. Active Polymer Center for Pattern Integration (APCPI), Yonsei-ro 50, Seodaemun-gu, Seoul 03722, Republic of Korea;1. Institute of Oceanology, Chinese Academy of Sciences, Qingdao 266071, China;2. School of Chemistry & Chemical Engineering, Henan Institute of Science and Technology, Xinxiang 453003, China;1. Department of Polymer Engineering and Color Technology, Amirkabir University of Technology, Tehran, Islamic Republic of Iran;2. Department of Chemical Engineering, Amirkabir University of Technology, Tehran, Islamic Republic of Iran |
| |
| Abstract: | The structure of the 01s spectrum for the MC 540 merocyanine dye is resolved using data obtained from XPS analysis of a series of merocyanine dyes displaying less complex O1s signals.The 01s binding energy (BE) of the carbonyl group in these molecules is unusually low and the photoionization peak is accompanied in most cases by a satellite on the high BE side.The data obtained in this study permit a reconstruction of the 01s profile of the MC 540 molecule. The 01s binding energy thus obtained for the carbonyl groups in MC 540 is 531.2 eV. This BE is low when compared to those usually observed for such groups and indicates that, in the MC 540 molecule, they predominantly exist in the ⩾C-O−3 form. |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
