Separation of inorganic anions on hydrophobic stationary phases in ion chromatography |
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Authors: | Toyohide Takeuchi Boran Jiang Lee Wah Lim |
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Institution: | (1) Department of Chemistry, Faculty of Engineering, Gifu University, 1-1 Yanagido, Gifu 501-1193, Japan |
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Abstract: | Inorganic anions were separated on hydrophobic stationary phases such as triacontyl-functionalized silica. Eluent conditions
were examined in detail, and iodate, nitrate, iodide, and thiocyanate could be separated by using aqueous solutions. The effect
of the eluent concentration on the retention of analyte anions was examined for a wide range of sodium sulfate concentrations
of up to 1 M. The retention factor of hydrophobic anions decreased with increasing sodium sulfate concentration in the lower
concentration region, while it increased with increasing sodium sulfate concentration in the higher concentration region.
The addition of a small amount of an organic substance such as acetonitrile and tetraethylene glycol increased the retention
of iodide and thiocyanate, while the addition of alcohols decreased their retention. Operating at lower temperature also increased
the retention of analyte anions. It was expected that inorganic anions were retained on the stationary phase via hydrophobic
interactions. The retention mechanism was discussed, considering the results obtained. |
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Keywords: | |
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