Abstract: | The meltinglike transition in unsupported icosahedral Na(N)() clusters, with N = 135-147, has been studied by isokinetic molecular dynamics simulations based on an orbital-free version of density functional theory. A maximum in the melting temperature, T(m), is obtained for Na141, while the latent heat, deltaE, and entropy of melting, deltaS, are maximal for Na147. These observations are in close agreement with calorimetric experiments on N clusters. The size evolution of deltaS is rationalized by the emergence of important premelting effects associated with the diffusive motion of atomic vacancies at the cluster surface. The precise location of the maximum in T(m) is explained in terms of two different thermally activated structural instability mechanisms which trigger the meltinglike transition in the size ranges N = 135-141 and N = 141-147, respectively. |