| The Solvent Effect on the Chemoselectivity of Palladium-catalyzed Oligomerization of 3, 3-Dimethyl-l-butyne |
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| 作者姓名： | JinShengCHENG JinHengLI HuanFengJIANG XiaoYueOUYANG |
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| 作者单位： | [1]LCLC,GuangzhouInstituteofChemistry,ChineseAcademyofSciences,Guanazhou510650 [2]StateKeyLaboratoryofOrganometallicsChemistry,ShanghaiInstituteofOrganicChemistry,ChineseAcademyofSciences,Shanghai200032 |
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| 摘 要： | The chemoselectivities of PdCl2 and CuCl2-catalyzed oligomerization of 3, 3-dimethyl-butyne: 1, 3, 5-tri-tert-butylbenzene, 2, 2, 7, 7-tetramethyl-3, 6-dichloro-3, 5-octadiene and 2, 2, 7,7- tetramethyl-3, 5-octadiyne were obtained, respectively, by regulating the polarity of the solvent.
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| 关 键 词： | 溶剂效应 化学选择性 钯 催化剂 低聚合作用 3 3-二甲基-l-丁炔 反应机理 晶体结构 |
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