Nickel-oxido structure of a water-oxidizing catalyst film |
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Authors: | Risch Marcel Klingan Katharina Heidkamp Jonathan Ehrenberg David Chernev Petko Zaharieva Ivelina Dau Holger |
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Affiliation: | Freie Universit?t Berlin, FB Physik, Arnimallee 14, 14195 Berlin, Germany. |
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Abstract: | The atomic structure of an electrodeposited Ni catalyst film is dominated by extensive di-μ-oxido bridging between Ni(III/IV) ions, as revealed by X-ray absorption spectroscopy. The structure is surprisingly similar to that of an analogous Co-based film and colloidal Mn-based catalysts. Structural requirements for water oxidation are discussed. |
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