Redox troponization of 4-methyl-4-dibromomethyl-2,5-cyclohexadien-1-one by the action of Pd(PPh3)4 |
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| Authors: | V A Nikanorov G V Gavrilova V I Rozenberg O A Reutov |
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| Institution: | (1) A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow |
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| Abstract: | Conclusions The feasibility of using gem-dihalomethyl-substituted cyclohexadienones in redox troponization reactions was shown in the case of the reaction of 4-methyl-4-dibromomethyl-2,5-cyclohexadien-1-one with Pd(PPh3)4, leading to the formation of 4-methy1-2,4,6-cycloheptatrien-1-one.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2345–2346, October, 1987. |
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